Semiconductor Physics, Quantum Electronics & Optoelectronics. 2005. V. 8, N 2. P. 007-011.
Defect structure of Czochralski silicon
co-implanted with helium and hydrogen
and treated at high temperature - pressure
1Institute of Electronic Materials Technology, Wolczynska 133, PL-01-919 Warsaw, Poland
Abstract. Effect of stress created by Ar hydrostatic pressure (HP) up to 1.1 GPa during
annealing at the high temperature (HT) 1070 K (HT-HP treatment) on microstructure of
Czochralski grown silicon co-implanted with helium and hydrogen Si:(He,H) using the
same doses of He+
and H2
+
(DH,He= 5·1016 cm–2, at energy 50 and 150 keV, respectively)
was investigated by means of X-ray (synchrotron) diffraction, transmission electron
microscopy, and electrical measurements. The nanostructured sponge-like buried layers
are formed in Si:(He,H) by annealing / high pressure treatment. Decreased interference,
diffuse scattering and individual contrast are observed in the synchrotron topograms for
HT-HP treated Si:(He,H). The treatment at 723 K and HP results in an additional donor
formation as a sequence of the implantation-disturbed layer. The HP-mediated (retarded)
out-diffusion of hydrogen and helium is in part responsible for the effects observed.
Keywords: Cz-Si, hydrogen, helium, implantation, diffusion, high pressure, treatment.
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