TY - JOUR TI - Electronic and magnetic properties of Zn1−xMnxSe:Fe2+,Cr2+ (x = 0.3) single crystals T2 - Semiconductor Physics, Quantum Electronics & Optoelectronics AU - Savchenko, D.V. AU - Ivanchenko, I.V. AU - Popenko, N.A. AU - Bekirov, B.E. AU - Kalabukhova, E.N. VL - 27 IS - 2 SP - 151 EP - 156 PY - 2024 DA - 2024 DO - 10.15407/spqeo27.02.151 UR - https://doi.org/10.15407/spqeo27.02.151 AB - We report the first study of Zn1−xMnxSe:Fe2+,Cr2+ (x = 0.3) crystals by continuous wave (CW) and pulsed electron paramagnetic resonance (EPR) spectroscopic techniques. Using the advantages of pulsed EPR, spin Hamiltonian parameters for Mn2+ ions were obtained (g∥ = g⊥ = 2.0060(3), А∥ = А⊥ = 61.84·10–4 cm–1, and D = –7.1·10–4 cm–1). The temperature dependence of the spin relaxation times of Mn2+ ions was described using the Orbach process for TM–1 and the Raman mechanisms for T1–1. The spin Hamiltonian parameters for Cr2+ ions were determined from the analysis of the angular dependence of CW EPR spectra (g⊥ = 1.98, g∥ = 1.961, D = –2.48 cm–1, and a = 0.02 cm–1). Moreover, an anisotropic ferromagnetic resonance (FMR) line was observed, the nature of which has yet to be clarified. KW - EPR KW - transition metals KW - zinc selenide ER -