TY  - JOUR
AU  - I.P. Studenyak
AU  - A.I. Pogodin
AU  - I.A. Shender
AU  - M.J. Filep
AU  - O.P. Kokhan
AU  - P. Kopčanský
TI  - Electrical properties of cation-substituted Ag 7 (Si 1-x Ge x )S 5 I single crystals
T2  - Semiconductor Physics, Quantum Electronics & Optoelectronics
VL  - 24
IS  - 3
SP  - 241
EP  - 247
PY  - 2021
DO  - 10.15407/spqeo24.03.241
UR  - https://doi.org/10.15407/spqeo24.03.241
AB  - High-quality single crystals of Ag7(Si1–xGex)S5I (x = 0.2, 0.4, 0.6, 0.8) solid solutions are grown from the solution–melt by vertical zone crystallization method. The measurements of electrical conductivity of Ag7(Si1–xGex)S5I solid solutions were performed using the impedance spectroscopy method within the frequency range from 10 Hz up to 2·106 Hz and temperature interval 293–383 K. Ionic and electronic components of electrical conductivity, as well as their ratios, were determined using the Nyquist plots.
KW  - argyrodites
KW  - crystal structure
KW  - superionic conductors
KW  - cationic substitution
KW  - electrical conductivity
ER  -