Semiconductor Physics, Quantum Electronics & Optoelectronics, 28 (1), P. 010-018 (2024).
DOI: https://doi.org/10.15407/spqeo28.01.010


Ferroelectric nanoparticles in liquid crystals: Role of ionic transport at small nanoparticle concentrations

Ju.M. Gudenko1, O.S. Pylypchuk1, V.V. Vainberg1, I.A. Gvozdovskyy1, S.E. Ivanchenko2, D.O. Stetsenko1, N.V. Morozovsky1, V.N. Poroshin1, E.A. Eliseev2*, and A.N. Morozovska1**

1Institute of Physics, National Academy of Sciences of Ukraine,
46 Nauky Avenue, 03028 Kyiv, Ukraine
2Frantsevich Institute for Problems in Materials Science, National Academy of Sciences of Ukraine,
3Omeliana Pritsaka Street, 03142 Kyiv, Ukraine
Corresponding author e-mail: eugene.a.eliseev@gmail.com*, anna.n.morozovska@gmail.com**



Abstract. We reveal an apparent influence of ultra-small concentrations (1 wt.% or less) of BaTiO3 nanoparticles (average size of 24 nm) on the current-voltage characteristics and capacitance of dielectric liquid crystal (LC) 5CB. A pure LC cell demonstrates higher current (and, hence, smaller resistance) as compared to LC cells filled with very small concentrations (0.5 and 1 wt.%) of BaTiO3 nanoparticles. The same trend is observed for the charge-voltage characteristics: the capacitance loop is the widest for the pure LC cell and becomes noticeably thinner in the presence of 0.5 and 1 wt.% of BaTiO3 nanoparticles. This seems counterintuitive, because 1 wt.% of ferroelectric nanoparticles modify the effective dielectric response very slightly and therefore should not influence on the director distribution and elastic properties of the LC. We conclude that a possible physical reason of this observation is the influence on the ionic transport in the LC of the ionic-electronic screening charges, which cover the ferroelectric nanoparticles and become polarized in an external field.

Keywords: dielectric liquid crystal, ferroelectric nanoparticles, BaTiO3 nanoparticles, current-voltage characteristics, ionic transport.

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