Semiconductor Physics, Quantum Electronics & Optoelectronics. 2011. V. 14, N 2. P. 256-260.
Dielectric and electro-optical properties of solutions
of chemically modified fullerene С60 in nematic liquid crystal
1Institute of Physics, NAS of Ukraine,
46, prospect Nauky, 03028 Kyiv, Ukraine
Abstract.
Solutions of fullerene molecules С60 with chemically attached molecules of
diamine (С60D) in planar oriented nematic liquid crystal (NLC) were obtained by only
heating and ultrasonic processing. The С60D concentration changes from 0 up to
3.0 wt.%. Within the ranges of frequencies 10 –1 – 10 6 Hz and temperatures 298-343 K,
dielectric properties of solutions were investigated. It was shown that, at frequencies
higher than 100 Hz, the frequency dispersion of the components of complex dielectric
permittivity is absent. A value of conductivity of the solution was determined. It was also
shown that the activation energy for the temperature dependence of the conductivity in
nematic and isotropic phases does not depend on the concentration of molecules С60D.
Obtained and explained were the reasons of the nonmonotonic conductivity dependence
of solutions on the concentration of С60D molecules. For frequencies lower than 100 Hz,
the dispersion of the components of complex dielectric permittivity is observed. It was
shown that the dispersion can be described by the Debye equation. The temperature
dependence of a value inverse to the relaxation time correlates with the temperature
dependence of conductivity. Presence of С60D molecules in NLC tends to increasing the
voltage for the Frederiksz transition. Made was the assumption that this effect may be
explained by increase in viscosity of NLC as a consequence of aggregation of fullerene
molecules.
Keywords: fullerene molecule, nematic liquid crystal, dielectric and electro-optical
properties.
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