Semiconductor Physics, Quantum Electronics & Optoelectronics, 5 (4), P. 457-464 (2002)
https://doi.org/10.15407/spqeo5.04.457


Semiconductor Physics, Quantum Electronics & Optoelectronics. 2002. V. 5, N 4. P. 457-464.

PACS: 73.40.Ns, 73.30.+y

Evolution of structural and electrophysical parameters of Ni/SiC contacts at rapid thermal annealing
V.L. Litvinov1, K.D. Demakov1, O.A. Agueev2, A.M. Svetlichny2, R.V. Konakova3, P.M. Lytvyn3, O.S. Lytvyn3, V.V. Milenin3

1Scientific & Research Center of Information Technologies "Kurchatov Institute", 123182 Moscow, Russia
2Taganrog State Radio Engineering University, Taganrog GSP-17A, Rostov Region, Russia
3Institute of Semiconductor Physics, NAS of Ukraine, 45 prospect Nauky, 03028 Kyiv, Ukraine
Phone: +38(044) 265 5940; fax: +38(044) 265 8342; e-mail: plyt@isp.kiev.ua

Abstract. Using X-ray phase analysis, Auger electron spectroscopy and atomic force microscopy, we investigated structural-phase transformations in the Ni/n-21R-SiC system induced by rapid thermal annealing in a vacuum (pressure of 10-2 Pa) in the 450-1100 °Ñ temperature range. It was found that modification of contact I-V curves from barrier-type to ohmic is due to appearance of local contact areas with different barrier heights (among them areas with ohmic conduction). Generation of the above nonuniformities results from intense heterodiffusion of the system components, as well as formation and recrystallization of various nickel silicide phases (differing in stoichiometry) and degradation of planar uniformity of both interface and Ni film.

Keywords: Ni/SiC contact, Schottky barrier, nickel silicides, rapid thermal annealing (RTA), X-ray phase analysis, Auger analysis, atomic force microscopy.
Paper received 15.11.02; accepted for publication 17.12.02.

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