Semiconductor Physics, Quantum Electronics & Optoelectronics. 2013. V. 16, N 4. P. 336-343.
DOI: https://doi.org/10.15407/spqeo16.04.336/

Magnetic-ordered and superconducting units inside surface layers of PbTe:Eu crystals grown from melt by using the Bridgman method
D.M. Zayachuk1, O.S. Ilyina1, D. Kaczorowski2, V.I. Mikityuk3, and V.V. Shlemkevych3

1Lviv Polytechnic National University, 12, Bandera str., 79013 Lviv, Ukraine Phone: +38 (032) 258-21-13; fax: +38 (032) 258-26-80; e-mail: zayachuk@polynet.lviv.ua
2Institute of Low Temperature and Structure Research, Polish Academy of Sciences, 50-950 Wroclaw 2, P. O. Box 1410, Poland
3Yuri Fedkovich Chernivtsy National University, 2, Kotsyubynskoho str., 58012 Chernivtsy, Ukraine

Abstract. Presented in this work are the results of the first systematic study of magnetic properties inherent to surface layers of PbTe:Eu crystals grown from melt with a low initial concentration of Eu impurity Nint Eu (about 1·1019 cm–3) using the Bridgman method. The magnetic field dependences of magnetization at the temperature 1.72 °K and temperature dependences of magnetic susceptibility within the temperature range 1.7 to 10 °K of the surface powder samples has been investigated. Inside the surface layers, formation of both small magnetic complexes based on Eu impurity and lead-based inclusions superconducting at low temperatures, which originate in a correlated way during the growth process of doped ingots, has been established. The observed correlations are manifested in a consistent distribution of both europium-based and lead-based units along the lateral surface, where the probability of their formation increases towards the end of the doped ingot. Based on the analysis of the obtained magnetic data, it has been suggested that the lead-based inclusions, being formed within the surface layer of PbTe:Eu crystals during the process of their growth and passing into a superconducting state on cooling, are the type II superconductors with a very high top critical field Hc2 at low temperatures. At T = 1.7 °K, Hc2 of the inclusions is estimated to exceed 50.0 kOe. The important role of the background oxygen impurity in formation of magnetic properties of the surface layers of PbTe:Eu crystals has been suggested.

Keywords: IV-VI crystals, surface, rare earth impurities, magnetization, magnetic susceptibility, magnetic complexes, superconducting inclusions.

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