Semiconductor Physics, Quantum Electronics & Optoelectronics, 26 (1), P. 114-119 (2023).
Utilizing machine learning algorithm in predicting the power conversion efficiency limit of a monolithically
perovskites/silicon tandem structure
1The Renewable Energy Postgraduate programme and the FabLab in the Centre for Emerging Learning Technologies Abstract.
Tandem structures have been introduced to the photovoltaics (PV) market to
boost power conversion efficiency (PCE). Single-junction cells’ PCE, either in a
homojunction or heterojunction format, are clipped to a theoretical limit associated with the
absorbing material bandgap. Scaling up the single-junction cells to a multi-junction tandem
structure penetrates such limits. One of the promising tandem structures is the perovskite
over silicon topology. Si junction is utilized as a counter bare cell with perovskites
layer above, under applying the bandgap engineering aspects. Herein, we adopt
BaTiO 3 /CsPbCl 3 /MAPbBr 3 /CH 3 NH 3 PbI 3 /c-Si tandem structure to be investigated. In
tandem PVs, various input parameters can be tuned to maximize PCE, leading to a massive
increase in the input combinations. Such a vast dataset directly reflects the computational
requirements needed to simulate the wide range of combinations and the computational
time. In this study, we seed our random-forest machine learning model with the 3?10 6
points’ dataset with our optoelectronic numerical model in SCAPS. The machine learning
could estimate the maximum PCE limit of the proposed tandem structure at around 37.8%,
which is more than double the bare Si-cell reported by 18%.
Keywords:tandem solar cells, numerical modeling, perovskites, random-forest algorithm,
crystalline silicon. This work is licensed under a Creative Commons Attribution-NoDerivatives 4.0 International License.
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