Semiconductor Physics, Quantum Electronics & Optoelectronics, 20 (3), P. 375-381 (2017).
DOI: https://doi.org/10.15407/spqeo20.03.375


The influence of the guest cavitations loading degree in fractal nanohybrids GaSe<β-cyclodextrin<FeSO4>> on the current passing and polarization processes. The giant “battery spin” effect at room temperature.
F.O. Ivashchyshyn1, I.I. Grygorchak1, O.I. Hryhorchak2

1Lviv Polytechnic National University, 12, Bandera Str., Lviv 79013, Ukraine
2Ivan Franko National University of Lviv, 8, Kyrylo and Mefodiy str., 79005 Lviv, Ukraine tor Physics, Chemnitz University of Technology, D-09107 Chemnitz, Germany E-mail: studenyak@dr.com

Abstract. The investigation results of clathrate properties GaSeβ-cyclodextrinFeSO4 of the hierarchical architecture with the fourfold expansion at different degrees of a guest cavitations loading have been presented. Based on the frequency dependence of the specific complex impedance, the changes of the impurity energy spectrum expanded matrix parameters as a result of forming the supramolecular ensembles on its basis are clarified. For some architecture, impedance, photo and magneto responses showed the extraordinary behavior of the magnetoimpedance and photoconductivity and also the giant negative photodielectric and the colossal magnetocapacitance effects at room temperature, which open new possibilities of their practical application.

Keywords: layered semiconductor GaSe, β-cyclodextrin, “host-guest” system, hierarchical architecture, impedance, Nyquist’s diagram, dielectric constant, tangent of angle of electric losses, photodielectric effect, magnetocapacity, “battery-spin” effect.

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