Semiconductor Physics, Quantum Electronics & Optoelectronics. 2009. V. 12, N 4. P. 412-416.
https://doi.org/10.15407/spqeo12.04.412


Thermodynamic analysis of processes creating the defects in cadmium telluride crystals under conditions of high-temperature annealing
V.V. Prokopiv1, P.M. Fochuk2, I.V. Gorichok1, E.V. Vergak2

1V. Stefanyk Precarpathion National University, 57, Shevchenko str., 76000 Ivano-Frankivsk, Ukraine; e-mail: goritchok@rambler.ru
2Institute of Inorganic Chemistry, Chernivtsi National University, 2, Kotsiubynsky str., 74012 Chernivtsi, Ukraine; e-mail: fochukp@gmail.com

Abstract. The defective structure of specifically undoped cadmium telluride crystals was researched using the theory of thermodynamic potentials. The calculated concentration of point defects and free charge carriers in the CdTe crystals, depending on technological factors of two-temperature annealing (annealing temperature T and partial pressure of cadmium P Cd vapor). The dominant types of defects that determine the basic properties of the material n- and p-type conduction were determined.

Keywords: two-temperature annealing, thermodynamic potential, point defects, electrical properties, cadmium telluride.

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